Technologies used at advanced dairy farms for optimizing the performance of dairy animals: A review

Superior germplasm, better nutrition strategies, health care facilities and improved dairy husbandry practices have boosted milk yield and its quality with a rapid rate. Per cow productivity has risen up sharply with considerable increase in the population of dairy animals. Recent era has witnessed the extension of large dairy farms around the world. Demand for high quality and increased quantity of milk is of the prime concern for all the dairy farms. With an increase in the size of animals in a farm, the labour requirement also rises up. Availability of skilled labour at low wage rate is becoming difficult. In last couple of decades, the cost of microprocessors has been reduced to an affordable level. The economic availability of engineered processors, artificial intelligence, improved data statistics combined with expert suggestions has created a revolution in livestock farming. Advanced engineered devices have become alternative to reduce high labour cost. This review focuses on latest knowledge and emerging developments in animal’s welfare focused biomarker activities and activity-based welfare assessment like oestrus, lameness and others. Use of enhanced sensors and data technologies with expert based solutions is anticipated to bring out a substantial improvement in existing dairy farming practices

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Barrierless Proton Transfer in the Weak C–H···O Hydrogen Bonded Methacrolein Dimer upon Nonresonant Multiphoton Ionization in the Gas Phase

Intermolecular proton transfer (IMPT) in a C–H···O hydrogen bonded dimer of an α,β-unsaturated aldehyde, methacrolein (MC), upon nonresonant multiphoton ionization by 532 nm laser pulses (10 ns), has been investigated using time-of-flight (TOF) mass spectrometry under supersonic cooling condition. The mass peaks corresponding to both the protonated molecular ion [(MC)­H⁺] and intact dimer cation [(MC)₂]^•+ show up in the mass spectra, and the peak intensity of the former increases proportionately with the latter with betterment of the jet cooling conditions. The observations indicate that [(MC)₂]^•+ is the likely precursor of (MC)­H⁺ and, on the basis of electronic structure calculations, IMPT in the dimer cation has been shown to be the key reaction for formation of the latter. Laser power dependences of ion yields indicate that at this wavelength the dimer is photoionized by means of 4-photon absorption process, and the total 4-photon energy is nearly the same as the predicted vertical ionization energy of the dimer. Electronic structure calculations reveal that the optimized structures of [(MC)₂]^•+ correspond to a proton transferred configuration wherein the aldehydic hydrogen is completely shifted to the carbonyl oxygen of the neighboring moiety. Potential energy scans along the C–H···O coordinate also show that the IMPT in [(MC)₂]^•+ is a barrierless process